Advances in Carbohydrate Chemistry, Vol. 5 - download pdf or read online

By Claude S. Hudson, etc.

ISBN-10: 012007205X

ISBN-13: 9780120072057

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Extra resources for Advances in Carbohydrate Chemistry, Vol. 5

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19) N. Kriukova, Biokhimiya, 6, 574 (1940). (20) M. Doudoroff, N. Kaplan and W. Z. Hassid, J. Biol. , 148, 67 (1943). 34 W. Z. HASSID AND M. DOUDOROFF D-glucose-1-phosphate and D-fructose, Hassid, Doudoroff and Barker’? succeeded in crystallizing a non-reducing disaccharide which was indistinguishable from natural sucrose. It was thus that the first laboratory synthesis of sucrose was achieved. The formation of Pglucose-1-phosphate and D-fructose from sucrose and inorganic phosphate, similar to the phosphorolysis of starch21 and glycogen,22may be considered to occur as the result of phosphorolytic cleavage of D-glucose from the sucrose molecule, the sucrose being disrupted without water entering into the reaction.

4. a-D-Glucopyranosyl-a-L-sorbofuranoside. . . . . . . . . VI. Synthetic Reducing Disaccharide. . . . . . . . . . . . . . . 3- [a-~-G~ucopyranosyl]-~-arabinopyranose. VII. Formation of Sucrose and Other Disaccharides through Exchange of Glycosidic Linkages. . . . . . . . . . . . . . . . . . . . . . . . 29 31 33 35 36 36 36 37 38 39 41 41 43 43 46 I. INTRODUCTION Sucrose is commercially the most important and quantitatively the most abundant sugar in the vegetable kingdom.

A. Preparation of the Enzymatic Extract from Pseudomonas saccharophila . . . . . . . . . . . . b. Enzymatic Synthesis and Isolation of Synthetic Sucrose. . . . c. Properties of Synthetic Sucrose ................... 2. a-D-Glucopyranosyl-D-D-xyloketofuranoside.. . . . . . . 3. , . . . . . . . . . . . . 4. a-D-Glucopyranosyl-a-L-sorbofuranoside. . . . . . . . . VI. Synthetic Reducing Disaccharide. . . . . . . . . . . . . . .

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Advances in Carbohydrate Chemistry, Vol. 5 by Claude S. Hudson, etc.


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